The first game to allow players to control one of Spidey’s deadly foes was Spider-Man & Venom: Maximum Carnage, published for the SNES and Mega Drive/Genesis in 1994. In the game, Spider-Man teams up with Venom to stop Carnage, and the game allowed players to choose which character they played as, enabling them to control Venom for the first time.
Guinness World Records Gamers’ Edition 2009.